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Journal of Functional Materials. 2013, (16) Core

The effects of core/shell ratio on rheological properties and gelation of polyacrylate plastisolChinese Full Text

SONG Xiao-li1,CHENG Zeng-hui1,CHEN Ri-qing1,WANG Chun-peng1,2(1.Institute of Chemical Industry of Forest Products,Chinese Academy of Forestry;National Engineering Laboratory for Biomass Chemical Utilization;Key and Open Laboratory on Forest Chemical Engineering, State Forestry Administration,Jiangsu Province Key Laboratory of Biomass Energy Sources and Materials, Nanjing 210042,China; 2.Research Institute of Forestry New Technology,Chinese Academy of Forestry,Beijing 100091,China)

Abstract: Different polyacrylate latexes with core-shell structure were prepared by semi-continuous seed emulsion copolymerization using various core/shell ratios（the ratio to monomer is 10/0,8/2,7/3,6/4,5/5 respectively）.The effects of core/shell ratio on the rheological behavior and gelationconversion of polyacrylate plastisol were investigated by rotary rheometer.The size and morphology of latex particle and plastisol surface membrane were characterized by dynamic light scattering（DLS） and scanning ele... More
Keywords：

core/shell ratio; plastisol; polyacrylate; rheological-gelation;

  • Series：

    (B) Chemistry/ Metallurgy/ Environment/ Mine Industry

  • Subject：

    Organic Chemical Industry

  • Classification Code：

    TQ325.7

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