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Chemistry and Industry of Forest Products. 2015, (05) Core

Frontier Orbital Energy Levels of Dehydroabietic Acid-based DiarylaminesChinese Full Text

GAO Hong;SHEN Ming-gui;WANG Xian-kai;SONG Zhan-qian;SHANG Shi-bin;Institute of Chemical Industry of Forest Products,CAF;National Engineering Lab.for Biomass Chemical Utilization;Key and Open Lab.of Forest Chemical Engineering,SFA;Key Lab.of Biomass Energy and Material;

Abstract: Band edges and onset oxide potentials of compounds a- g were studied through UV-Vis spectra and cyclic voltammetry curve. Their highest occupied and lowest unoccupied molecular orbital（ HOMO / LUMO） levels as well as energy gaps were calculated by empirical formula,and the relationship between energy gaps and fluorescent properties were discussed. The results showed that compounds e and f with big conjugated naphthalene and biphenyl and compounds b and g with methoxy and methyl substituent group... More
Keywords：

dehydroabietic acid-based diarylamine; cyclic voltammetry; frontier orbital; energy gap; fluorescent property;

  • Series：

    (B) Chemistry/ Metallurgy/ Environment/ Mine Industry

  • Subject：

    Chemistry

  • Classification Code：

    O625.6

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